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Mössbauer spectrometry insights into the redox reactivity of Fe-bearing phases in the environment

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  • FOCUS ISSUE: Mössbauer Spectroscopy from Artificial Nano Architectures to Environmental Applications
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Abstract

Rates and mechanisms of important reactions in the cycling of electrons via the geochemical transformations of iron have been identified using Mössbauer spectrometry. The cycling of iron through various reservoirs (aquifer, soils, sediments, claystone) depends on high surface-area-to-volume ratios of Fe-bearing solids. The ability of Fe-bearing solids surfaces to interact chemically, through surface complexation, and ligand exchange mechanisms, with reductants such as FeII, and oxidants such as Se, U, Tc, Co, Eu, and O2 facilitates electron transfer as well as dissolution and precipitation. Various pathways have been assessed on the basis of laboratory experiments for application to natural and engineered systems. FeII in the structure of layered silicates, oxides (e.g., Fe3O4) and hydrous oxides, and sulfides, as well as FeII surface complexes, such as on clay mineral edges, are very efficient reductants from a thermodynamic as well as from a kinetic point of view.

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Funding

Support and funding from ANDRA and NAGRA for many years is greatly appreciated. This work benefited from funding of EURAD—European Union’s Horizon 2020, Grant Agreement No 847593 (WP FUTURE). CT acknowledges a Grant overseen by the French National Research Agency (ANR) as part of the “Investissements d’Avenir” Programme LabEx VOLTAIRE, 10-LABX-0100 at ISTO.

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  1. Univ. Grenoble Alpes, Univ. Savoie Mont Blanc, CNRS, IRD, Univ. Gustave Eiffel, ISTerre, 38000, Grenoble, France

    Laurent Charlet & Antoine Géhin

  2. Institut des Sciences de la Terre d’Orléans (ISTO), Université d’Orléans, CNRS, BRGM, Orléans, France

    Laurent Charlet & Christophe Tournassat

  3. Earth and Environmental Sciences Area, Lawrence Berkeley National Laboratory, Berkeley, CA, USA

    Christophe Tournassat

  4. Institut des Molécules et Matériaux du Mans, IMMM UMR CNRS 6283, Le Mans Université, Le Mans Cedex 9, France

    Jean-Marc Grenèche

  5. University of Bern, Bern, Switzerland

    Paul Wersin & Jebril Hadi

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Charlet, L., Tournassat, C., Grenèche, JM. et al. Mössbauer spectrometry insights into the redox reactivity of Fe-bearing phases in the environment. Journal of Materials Research 38, 958–973 (2023). https://doi.org/10.1557/s43578-022-00823-8

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