Abstract
Taking into account the bilinear coupling between the tunneling protons and the displacements of the electron shells of the surrounding groups, we present a new model of hydrogen-bonded ferroelectrics. The model is an extension of both the tunneling model and the nonlinear polarizability model and includes the geometrical aspects of the hydrogen bond. It leads to a structural phase transition and describes the isotope effect due to the substitution in and the pressure dependence.
- Received 6 October 1997
DOI:https://doi.org/10.1103/PhysRevLett.80.2173
©1998 American Physical Society