Elsevier

Lithos

Volume 153, 15 November 2012, Pages 94-107
Lithos

Early Variscan I-type pluton in the pre-Alpine basement of the Western Alps: The ca. 360 Ma Cogne diorite (NW-Italy)

https://doi.org/10.1016/j.lithos.2012.04.010Get rights and content

Abstract

Located at the internal border of the Grand-Saint-Bernard Zone, the diorite and its aureole lie on top of intensively studied Alpine eclogitic units but this pluton, poorly studied yet, has kept locally almost undeformed. The pluton intruded, at ~ 360 Ma, country-rocks mostly composed of dark shales with Na2O > K2O and minor mafic intercalations of tholeiitic basalt affinity. This association is characteristic of the Vanoise (France) basement series, where available age determinations suggest an Early Paleozoic age. Parts of the pluton, and of its hornfels aureole that is evidenced here for the first time, in the Punta Bioula section of Valsavaranche valley (NW-Italy), have been well-preserved from the Alpine deformation. Syn-emplacement hardening, dehydration-induced, probably prevented strain-enhanced Alpine recrystallization. Magmatic rock-types range continuously from subordinate mafic types at SiO2 ~ 48%, of hornblendite with cumulative or appinite affinities, to the main body of quartz diorite to quartz monzonite (SiO2 up to 62%). P–T estimates for the pluton emplacement, based on the abundance of garnet in the hornfelses, using also zircon and apatite saturation thermometry and Al-in-hornblende barometry, suggest T ~ 800–950 °C and minimum P in the 0.2–0.5 GPa range, with records of higher pressure conditions (up to 1–2 GPa?) in hornblendite phlogopite-cored amphibole. The high-K, Na > K, calc-alkaline geochemistry is in line with a destructive plate-margin setting. Based on major element data and radiogenic isotope signature (εNd360 Ma from − 1.2 to + 0.9, 87Sr/86Sr360 Ma from 0.7054 to 0.7063), the parental magmas are interpreted in terms of deep-seated metabasaltic partial melts with limited contamination from shallower sources, the low radiogenic Nd-content excluding a major contribution from Vanoise tholeiites. There is no other preserved evidence for Variscan magmatism of similar age and composition in the Western Alps, but probable analogs are known in the western and northern parts of French Massif Central. Regarding the Alpine tectonics, not only the age of the pluton and its host-rocks (instead of the Permo-Carboniferous age previously believed), but also its upper mylonitic contact, suggest revisions of the Alpine nappe model. The Cogne diorite allegedly constituted the axial part of the E-verging “pli en retour [backfold] du Valsavaranche”, a cornerstone of popular Alpine structural models: in fact, the alleged fold limbs, as attested here by field and geochemical data, do not belong to the same unit, and the backfold hypothesis is unfounded.

Highlights

► A unique Early Variscan pluton in the Alps, I-type, at 360 Ma ► Emplacement P and T estimated around 0.35 GPa and 950 °C ► Maybe emplaced over subducting oceanic crust, from Rheic Ocean or Paleotethys ► Remains of deep source-rocks in cored amphibole of hornblendite ► This pluton is not the hinge of the Valsavaranche Backfold, now to be redrawn.

Introduction

Assessing the tectonic setting and P–T conditions of emplacement of granitoid bodies relies on a wide choice of methods. For fresh rocks, the study of mineral assemblages, mineral zoning and mineral chemistry may be privileged upon the consideration of “blind” whole-rock geochemical indicators. In case of secondarily metamorphosed plutons, this approach is not applicable any more, and it is necessary to use more indirect methods, based on immobile element contents at the whole rock scale, and refractory minerals. Here we attempt to characterize the Cogne diorite, a plutonic body that belongs to the polycyclic, pre-Triassic basement of the Western Alps, with special effort to separate the pre-Alpine heritage from the Alpine overprinting.

The Cogne diorite pluton crops out in the basement of the Middle Penninic Zone. Its igneous emplacement occurred near the Devonian–Carboniferous boundary, as documented by U–Pb zircon dating (Bertrand et al., 2000b) at ~ 360 Ma, so that this pluton is a rare, if not the only, piece of evidence of the early stage of the Variscan events in the Western Alps. Here we present new geochemical and petrological data for the Cogne diorite as an opportunity to assess the Early Carboniferous, or older, tectonic setting of yet poorly known pre-Alpine domains. In a context of Alpine high pressure and subduction-related nappes, tracing the origin of the units requires to take into account their protolith ages. A number of protolith age determinations have been obtained during the last decades on such pre-Alpine basement units, often with unexpected results, leading to various paleogeographic inferences (Bertrand et al., 2005, Michard and Goffé, 2005, Ring et al., 2005). It seems timely to unravel the pre-Alpine geological history of some of those recently dated units.

Section snippets

Geological context

Many unresolved questions arise from the location of the Cogne pluton in the internal zone of the Alpine orogen (Fig. 1, Fig. 2, Fig. 3, Table 1), inserted in a complex nappe stack. Regarding the Alpine events, P–T-t estimates of 1.5–3 GPa, 575 °C at 45–30 Ma have been published for the Gran Paradiso basement massif (Gabudianu Radulescu et al., 2009) and its Alpine cover (Angiboust et al., 2009, Beltrando et al., 2009). The determination of these eclogitic conditions is critical, because these

Materials and methods

About 150 polished thin sections were prepared from the samples collected along the Punta Bioula section, and about 50 of them were subjected to micro-chemical investigations using a scanning electron microscope equipped with an energy dispersive system for microanalysis and elemental mapping (SEM-EDS, Univ. Lille). Dubious mineral phases were also investigated by Raman spectroscopy (green laser 532 nm, model LabRam HR800, Univ. Lille). Fourteen whole-rock analyses (Table 2) were complemented by

Bulk composition melts

Not excluding a priori a mantle origin, identifying the type of a possible crustal source for the diorite can be attempted through a major element diagram (Fig. 10a) devised from a compilation of experimental melt analyses (Altherr et al., 2000). Among the nearby rocks, only the TPBU metavolcanite (anal. 14) plots alike melts from metagreywackes. The host-rock metapelites (anal. 12–13) plot inside the domain of Vanoise metapelites (denoted by “p” contouring in Fig. 10a), and the mafic level

I-type characters for the Cogne diorite

Based on a wealth of criteria, an I-type may be proposed for the Cogne diorite: a magmatic assemblage with amphibole, pale biotite, titanite, allanite ± epidote; no monazite and no muscovite; 0.7054 < 87Sr/86Sr360 < 0.7063, − 1.2 < εNd360 < + 0.9 (Barbarin, 1999, Clemens et al., 2011, McCulloch and Chappell, 1982). For comparison purposes, the I-type quartz-diorites of Limousin (Shaw et al., 1993) were plotted in the various diagrams (Fig. 7, Fig. 8, Fig. 9, Fig. 10). With SiO2-contents at 53–58% for seven

Acknowledgments

Jean-Luc Potdevin, Marie Lefranc and Monique Gentric (UMR 8110 PBDS-CNRS) helped in funding the analyses. The staff and director of the Parco Nazionale del Gran Paradiso have allowed sampling inside the Park and sheltered us in mountain refuges of Orvieille and Gran Nomenon. Renaud Caby (Montpellier) and Enzo Callegari (Torino) provided unpublished documentation, and Marco Malusà (Milano) proposed new ideas on the Alpine shear zones. Abdoulaye Baldé, Thomas Maurin, Bénédicte Knafel, Riccardo

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    Deceased, March 18th, 2011.

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