Issue 36, 2016
From the journal:

Dalton Transactions

Intramolecular Hg⋯π interactions of d-character with non-bridging atoms in mercury–aryl complexes†

A. Lannes,*ab   A. Manceau,*a   M. Rovezzi,c   P. Glatzel,c   Y. Jolyb  and  I. Gautier-Luneaub  

* Corresponding authors

a ISTerre, Université Grenoble Alpes, CNRS, CS 40700, 38058 Grenoble, France
E-mail: anthony.lannes@gmail.com, alain.manceau@univ-grenoble-alpes.fr

b Institut Néel, Université Grenoble Alpes, CNRS, 25 avenue des Martyrs, 38042 Grenoble, France

c European Synchrotron Radiation Facility (ESRF), 71 Rue des Martyrs, 38000 Grenoble, France

Abstract

Mercury 5d-orbitals are involved in intramolecular π-interactions with carbon and sulfur nearest and next-nearest neighbors in mercury–aryl complexes. This unexpected character of the electron cloud of mercury was revealed by high energy-resolution XANES spectroscopy readily interpreted in terms of a final-state local (l,m)-projected density of states (DOS).

Graphical abstract: Intramolecular Hg⋯π interactions of d-character with non-bridging atoms in mercury–aryl complexes

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C6DT02200F
Article type
Communication
Submitted
01 Jun 2016
Accepted
11 Aug 2016
First published
16 Aug 2016

Dalton Trans., 2016,45, 14035-14038

Permissions

Request permissions

Intramolecular Hg⋯π interactions of d-character with non-bridging atoms in mercury–aryl complexes

A. Lannes, A. Manceau, M. Rovezzi, P. Glatzel, Y. Joly and I. Gautier-Luneau, Dalton Trans., 2016, 45, 14035 DOI: 10.1039/C6DT02200F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements