Skip to main content
SpringerLink
Log in

2,2′-Diaminodiethylamine cellulose powder for trace metal preconcentrations from water

2,2′-Diaminodiethylamin-Cellulosepulver zur Anreicherung von Spurenmetallen aus Wasser

  • Original Papers
  • Published:
Fresenius' Zeitschrift für analytische Chemie Aims and scope Submit manuscript

Zusammenfassung

Cellulosepulver mit funktioneilen Gruppen von 2,2′-Diaminodiethylamin (DEN) weist eine wirkungsvolle Komplexierung von Kationen der Übergangsmetalle auf. Ausbeuten von mehr als 85 % werden erhalten bei einer Komplexierungskapazität bis zu 1,5 mÄq/g. Da bei pH-Werten über 5 gute Ausbeuten erzielt werden, sind bei natürlichen Wasserproben keine pH-Einstellungen erforderlich. Das DEN-Cellulosepulver ist unempfindlich gegen größere Konzentrationen von Alkali- und Erdalkaliionen sowie Huminverbindungen. Einige Kationen können in einem kleinen Volumen von Salpetersäure gut eluiert werden. Blindwerte für die DEN-Cellulose werden angegeben.

Summary

Cellulose powder with 2,2′-diaminodiethylamine (DEN) functional groups exhibits efficient complexation of transition metal cations. Collection yields above 85 % are obtained up to a chelation capacity of 1.5 meq per gram. Since a good collection is obtained for a pH up from 5, no pH adjustments have to be made for natural water samples. The cellulose-DEN powder is insensitive to abundant substances like alkali and alkaline earth ions, and humic matter. Some cations can be eluted efficiently in a small volume of HNO3. Blank concentration levels from the cellulose-DEN powder are reported.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Mizuike A (1983) Enrichment techniques for inorganic trace analysis. Springer, Berlin Heidelberg New York

    Google Scholar 

  2. Zolotov YA, Kyzmin NM (1982) Preconcentration of microelements. Khimia, Moscow

    Google Scholar 

  3. Bächmann K (1981) CRC Crit Rev Anal Chem 12:1

    Google Scholar 

  4. Van Grieken R (1982) Anal Chim Acta 143:3

    Google Scholar 

  5. Schwarzenbach G (1960) Anal Chem 32:6

    Google Scholar 

  6. Burba P, Willmer PG (1983) Talanta 30:381

    Google Scholar 

  7. Burba P, Lieser KH (1977) Fresenius Z Anal Chem 286:191

    Google Scholar 

  8. Lieser KH, Röber H-M, Burba P (1979) Fresenius Z Anal Chem 284:361

    Google Scholar 

  9. Smits JA, Van Grieken RE (1980) Anal Chem 52:1479

    Google Scholar 

  10. Smits J, Van Grieken R (1981) Intern J Environ Anal Chem 9:81

    Google Scholar 

  11. Van Espen P, Nullens H, Adams F (1977) Nucl Instrum Meth 142:243

    Google Scholar 

  12. Van Dyck PM, Van Grieken R (1980) Anal Chem 52:1859

    Google Scholar 

  13. Verbueken A (unpublished results)

  14. Smits J, Van Grieken R (1978) Angew Makromol Chem 72:105

    Google Scholar 

  15. Prue JE, Schwarzenbach G (1950) Helv Chim Acta 33:985

    Google Scholar 

  16. Cotton FA, Wilkinson G (1972) Advanced inorganic chemistry. Interscience Publishers: New York

    Google Scholar 

  17. Sillen LG, Martell AE (1964) Stability constants, Special publication no 17. The Chemical Society, Eondon

    Google Scholar 

  18. Sillen EG, Martell AE (1971) Stability constants, Suppl no 1, Special publication no 25. The Chemical Society, London

    Google Scholar 

  19. Smits J, Van Grieken R (1981) Anal Chim Acta 123:9

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Antwerp (U.I.A.), Universiteitsplein 1, B-2610, Wilrijk, Belgium

    G. Reggers & R. Van Grieken

Authors
  1. G. Reggers
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. Van Grieken
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Reggers, G., Van Grieken, R. 2,2′-Diaminodiethylamine cellulose powder for trace metal preconcentrations from water. Z. Anal. Chem. 317, 520–526 (1984). https://doi.org/10.1007/BF00511918

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00511918

Keywords

Search

Navigation