Abstract
A diffusive sampling method for the determination of gaseous acetic and formic acids, using a radial symmetry diffusive sampler, has been optimised for a 7-day exposure time in this study. Sampling rate determinations were performed on data obtained from a dynamic exposure chamber, simulating the indoor conditions of an empty, closed, room, at room temperature and minimal wind speed. Analysis has been performed by means of ion chromatography. The sampling rates for formic acid concentrations of 128 μg m−3 and 1248 μg m−3 were determined to be 91.2 ± 3.9 ml min−1 and 111.6 ± 2.8 ml min−1, respectively. The acetic acid sampling rate was independent of the concentration in the range 160 μg m−3–1564 μg m−3, and amounted to 97.3 ± 3.1 ml min−1. Experimentally determined sampling rates showed deviations of 3% for acetic acid, and 3–21% for formic acid, in relation to theoretically derived values. The blank values were as low as 1.69 ± 0.07 μg for formic acid and 1.21 ± 0.14 μg for acetic acid, and detection limits lower than 0.5 μg m−3 could be achieved, which is an improvement of 98–99% compared to previously validated diffusive sampling methods. This study describes the first step of an extended validation program in which the applicability of these types of samplers for the measurement of organic acids will be validated and optimised for the environmental conditions typical for museum showcases.
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Alexandrov, V. A., Nivikov, A. I., Zabezhinsky, M. A., Stolyarov, V. I., & Petrov, A. S. (1989). The stimulating effect of acetic acid, alcohol and thermal burn injury on esophagus and forestomach carcinogenesis induced by N-nitrososarcosin ethyl ester in rats. Cancer Letters, 47, 179–185.
Gair, A. J., Penkett, S. A., & Oyola, P. (1992). Development of a simple passive technique for the determination of nitrogen dioxide in remote continental location. Atmospheric Environment, 25A, 1927–1939.
Gibson, L. T., Cooksey, B. G., Littlejohn, D., & Tenner, N. H. (1997). A diffusive tube sampler for the determination of acetic and formic acid vapours in museum cabinets. Analytica Chimica Acta, 341, 11–19.
Kivity, S., Fireman, E., & Lerman, Y. (1994). Late asthmatic response to inhaled glacial acetic acid. Thorax, 49, 727–728.
Koenig, J. Q., Covert, D. S., & Pierson, W. E. (1989). Effects of inhalation of acetic acidic compounds on pulmonary function in allergic adolescent subjects. Environmental Health Perspective, 79, 173–178.
Larson, T. V. (1989). The influence of chemical and physical forms of ambient air acids on airway doses. Environmental Health Perspective, 79, 7–13.
Linden, C. H., Sullivan, J. B., & Krieger, G. R. (1992). Inorganic acids and bases, hazardous material toxicity. Clinical principles of environmental health, hazardous material toxicity, (pp. 762–774). Baltimore: Williams and Wilkins.
Nielsen, D. G., Friman Hansen, L., Anderson Nexø, B., & Melchior Poulsen, O. (1998). Indoor air guideline levels for formic, acetic, propionic and butyric acid. Indoor Air, S5, 8–24.
Reis, R., Ryan, P. B., Tibbetts, S. J., & Koutrakis, P. (1995). Measurement of organic acids, aldehydes, and ketones in residential environments and their relation to ozone. Journal of the Air & Waste Management Association, 45, 881–822.
Ryhl-Svendsen, M., & Glastrup, J. (2002). Acetic acid and formic acid concentrations in museum environment measured by SPME-GC-MS. Atmospheric Environment, 36, 3909–3916.
Utell, M. J. (1985). Effects of inhaled acid aerosols on lung mechanics: an analysis of human exposure studies. Environmental Health Perspective, 63, 39–44.
Van Bommel, M., Brugman, S., & Van Keulen, H. (2003). Emission of small organic volatiles from wooden construction materials in a small test chamber. In: Presentation abstracts of the IAQ in Museums and Historic Properties Conference; 5th meeting of the Indoor Air Pollution Working Group, University of East Anglia, School of Environmental Sciences, Norwich, April 28–29.
Van Bommel, M., Gibson, L., Watts, S., Kontozova, V., & Halsberghe, L. (2004). A comparison of diffusion tube determinations of formic and acetic acid concentrations in air. Paper presented at the IAQ in Museums and Archives conference, Padova, November 10–12.
Weschler, C. J., Brauer, M., & Koutrakis, P. (1992a). Indoor ozone and nitrogen dioxide: a potential pathway to the generation of nitrate radicals, dinitrogen pentaoxide and nitric acid indoors. Environmental Science Technology, 26, 179–184.
Weschler, C. J., Hodgson, A. T., & Wooley, J. D. (1992b). Indoor chemistry: ozone, volatile organic compounds, and carpets. Environmental Science Technology, 26, 2371–2377.
Wilke, R. C., & Lee, C. Y. (1955). Estimation of diffusion coefficients for gases and vapours. Industrial and Engineering Chemistry Research, 47, 1253–1257.
Zang, J., Wilson, W. E., & Lioy, P. J. (1994). Sources of organic acids in indoor air: a field study. Journal of Experimental Analysis of Environmental Epidemiology, 4, 25–47.
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Stranger, M., Potgieter-Vermaak, S., Sacco, P. et al. Analysis of indoor gaseous formic and acetic acid, using radial diffusive samplers. Environ Monit Assess 149, 411–417 (2009). https://doi.org/10.1007/s10661-008-0217-6
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DOI: https://doi.org/10.1007/s10661-008-0217-6