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Influence of the deposition method, temperature and deposition time on the corrosion inhibition of lead dodecanoate coatings deposited on lead surfaces

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Abstract

Electrochemical impedance measurements have been used to investigate the influence of the deposition method, including time and temperature, upon the corrosion inhibition characteristics of lead dodecanoate coatings on lead electrodes. The results were analysed using multivariate statistics and show that, in general, these easily prepared coatings are very protective against corrosion. The temperature proves to be an important parameter for the quality and the corrosion inhibition efficiency of the coating. A comparison between two different electrochemically assisted deposition methods, immersion using a reduction pretreatment and cyclic voltammetry, does not show significant differences. Using the immersion technique at room temperature, the deposition time was tested as the third influencing parameter for the corrosion inhibition efficiency of the deposited lead dodecanoate coatings. A longer deposition time of the lead into the sodium dodecanoate solution provides a layer with a somewhat higher corrosion resistance.

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References

  1. Abd El-Rehim S, Amin N, Ali L, Mohamed N (1998) Electrochemical behaviour and corrosion of lead in some carboxylic acid solutions. J Chem Technol Biotechnol 72:197–201

    Article  CAS  Google Scholar 

  2. Adriaens A, De Bisschop F, Dowsett M, Schotte B (2008) Growth and real time corrosion resistance monitoring of lead decanoate coatings. Appl Surf Sci 254:7351–7355

    Article  CAS  Google Scholar 

  3. Amuridin A, Thierry D (1995) Application of electrochemical impedance spectroscopy to study the degradation of polymer-coated metals. Prog Org Coat 26:1–28

    Article  Google Scholar 

  4. Antonijevic M, Petrovic M (2008) Copper corrosion inhibitors: a review. Int J of Electrochem Sci 3:1–28

    CAS  Google Scholar 

  5. ASTM International (2008) ASTM standards for corrosion and testing of metals: 3rd edition. International ASTM, West Conshohocken

  6. Badawy W, Hefny M, El-Egamy S (1990) Corrosion behaviour of Pb-Sn binary alloys in acid solutions. Corrosion 46:978–982

    Article  CAS  Google Scholar 

  7. Caroline M, Christian P, Hannes C, Boris K, Ilhan A (2008) Inhibition and promotion of copper corrosion by ctab in a microreactor system. Langmuir 24:14,269–14,275

    Google Scholar 

  8. Chauhan L, Gunasekaran G (2007) Corrosion inhibition of mild steel by plant extract in dilute HCl. Corros Sci 49(3):1143–1161

    Article  CAS  Google Scholar 

  9. Cheraghi B, Fakhari A, Borhani S, Entezami A (2009) Chemical and electrochemical deposition of conducting polyaniline on lead. J Electroanal Chem 626:116–122

    Article  CAS  Google Scholar 

  10. Chiavari C, Martini C, Poli G, Prandstraller D (2004). In: Ashton J , Hallam D (eds) Metal 04: proc. of the intern. conf. on metals conservation: conservation of organ pipes: protective treatments of lead exposed to acetic acid vapours, vol 3. National Museum of Australia Canberra Press

  11. De Keersmaecker M, De Wael K, Adriaens A (2012) The use of lead dodecanoate as an environmentally friendly coating to inhibit the corrosion of lead objects: comparison of three different deposition methods. Prog Org Coat 74:1–7

    Article  CAS  Google Scholar 

  12. De Wael K, De Keersmaecker M, Dowsett M, Walker D, Thomas PA, Adriaens A (2009) Electrochemical deposition of dodecanoate on lead in view of a environmentally safe corrosion inhibition. J Solid State Electrochem 14(3):407–413

    Article  Google Scholar 

  13. Dyshlovenko S, Pierlot C, Pawlowski L, Tomaszek R, Chagnon P (2006) Experimental design of plasma spraying and laser treatment of hydroxyapatite coatings. Surf Coat Technol 201:2054–2060

    Article  CAS  Google Scholar 

  14. Eftekhari A, Ahmadi I (2006) Electrodeposition of smooth and adherent film of polypyrrole on lead electrode. Prog Org Coat 57:371–375

    Article  CAS  Google Scholar 

  15. El Azhar M, Marnari B, Traisnel M, Bentiss F, Lagrenée M (2001) Corrosion inhibition of mild steel by the new class of inhibitors in acidic media. Corros Sci 43:2229–2238

    Article  CAS  Google Scholar 

  16. Elewady G, El-Said I, Fouda A (2008) Anion surfactants as corrosion inhibitors for aluminum dissolution in hcl solutions. Int J Electrochem Sci 3:177–190

    CAS  Google Scholar 

  17. Ellis H, White NA, Hassan I, Ahmed R (2002) A room temperature structure for anhydrous lead(II) decanoate. J Mol Struct 642:71–76

    Article  CAS  Google Scholar 

  18. Fawzy M, Sedahmed G, Mohamed A (1981) Corrosion behaviour of Pb-Sn binary alloys in acid solutions. Surf Technol 14:257–264

    Article  CAS  Google Scholar 

  19. Gece G (2008) The use of quantum chemical methods in corrosion inhibitor studies. Corros Sci 50:2981–2992

    Article  CAS  Google Scholar 

  20. Gomma G (1998) Influence of copper cation on inhibition of corrosion for steel in presence of benzotriazole in sulfuric acid. Mater Chem Phys 55(2):131–138

    Article  CAS  Google Scholar 

  21. Hamilton D (1999) Methods of conserving archeological material from underwater sites. Conservation files: ANTH 605, Conservation of Cultural Resources I. Nautical Archeology Program., Texas A&M University. http://nautarch.tamu.edu/class/ANTH605. Accessed January 2012

  22. Hsu C, Mansfeld F (2001) Technical note: concerning the conversion of the constant phase element parameter into a capacitance. Corros 57(9):747–748

    Article  CAS  Google Scholar 

  23. Lacoutre F, François M, Didierjean C, Rivera JP, Rocca E, Steinmetz J (2001) Anhydrous lead(II) heptanoate. Acta Crystallogr C Cryst Struct Commun 57:530–531

    Article  Google Scholar 

  24. Lorenz W, Mansfeld F (1986) Interface and interphase corrosion inhibition. Electrochim Acta 31(4):467–476

    Article  CAS  Google Scholar 

  25. Loveday D, Peterson P, Rodgers B (2004) Evaluation of organic coatings with electrochemical impedance spectroscopy. Part 2: application of EIS to coatings. J Coat Technol 10:88–93

    Google Scholar 

  26. Malik MA, Hashim MA, Nai F, Al-Thabaiti SA, Khan Z (2011) Anti-corrosion ability of surfactants: a review. Int J Electrochem Sci 6:1927–1948

    CAS  Google Scholar 

  27. Murray J (1997) Electrochemical test methods for evaluating organic coatings on metals: an update. Part III: multiple test parameter measurements. Prog Org Coat 31:375–391

    Article  CAS  Google Scholar 

  28. Nilsson A, Pettersson L, Norskov J (eds) (2008) Chemical bonding at surfaces and interfaces. Elsevier, Amsterdam

    Google Scholar 

  29. Paleska I, Pruszkowska-Drachal R, Kotowski J, Dziudzi A, Milewski J, Kopczyk M, Czerwiński A (2003) Electrochemical behaviour of lead alloys in sulfuric acid and phosphoric acid solutions. J Power Sources 113:308–317

    Article  CAS  Google Scholar 

  30. Rocca E, Steinmetz J (2001) Inhibition of lead corrosion with saturated linear aliphatic chain monocarboxylates. Corros Sci 43:891–902

    Article  CAS  Google Scholar 

  31. Rocca E, Rapin C, Mirabet F (2004) Inhibition treatment of the corrosion of lead artefacts in atmospheric conditions and by acetic acid vapour: use of sodium decanoate. Corros Sci 46:653–665

    Article  CAS  Google Scholar 

  32. Salim Akther M (1997) Effect of acetamide on the cmc of aqueous solutions of some surfactants. Colloids Surf A 121:103–109

    Article  Google Scholar 

  33. Sankarapapavinasam S, Ahmed M (1990) Tosylhydrazine as protector for lead in acetic acid vapours. J Elec Soc India 39(4):255–256

    CAS  Google Scholar 

  34. Sankarapapavinasam S, Pushpanaden F, Ahmed M (1989) Hydrazine and substituted hydrazines as corrosion inhibitors for lead in acetic acid. Br Corros J 24(1):39–42

    CAS  Google Scholar 

  35. Umoren S, Li Y, Wang FH (2010) Effect of polyacrylic acid on the corrosion behaviour of aluminium in sulphuric solution. J Solid State Electrochem 14:2293–2305

    Article  CAS  Google Scholar 

  36. Zhang DQ, Cai QR, He XM, Gao LX, Zhou GD (2008) Inhibition effect of some amino acids on copper corrosion in hcl solution. Mater Chem Phys 112:353–358

    Article  CAS  Google Scholar 

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Acknowledgements

The Research Foundation—Flanders (FWO)—and Ghent University are acknowledged for the funding of this work. The authors would also like to thank Pieter van Hoe for the construction of the lead electrodes.

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Authors and Affiliations

  1. Department of Analytical Chemistry, Ghent University, Krijgslaan, 281-S12, 9000, Ghent, Belgium

    M. De Keersmaecker & A. Adriaens

  2. Chemistry Department, University Antwerp, Universiteitsplein 1, 2160, Antwerp, Belgium

    K. De Wael

Authors
  1. M. De Keersmaecker
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  2. K. De Wael
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  3. A. Adriaens
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Correspondence to A. Adriaens.

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De Keersmaecker, M., De Wael, K. & Adriaens, A. Influence of the deposition method, temperature and deposition time on the corrosion inhibition of lead dodecanoate coatings deposited on lead surfaces. J Solid State Electrochem 17, 1259–1269 (2013). https://doi.org/10.1007/s10008-012-1964-4

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  • DOI: https://doi.org/10.1007/s10008-012-1964-4

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