THz Spectroscopy as a Versatile Tool for Filler Distribution Diagnostics in Polymer Nanocomposites
Abstract
:1. Introduction
2. Materials
2.1. Composites Fabrication
2.2. Sample Characterization
3. Experimental: Time-Domain THz Transmission Measurements
4. Modeling: MG Effective Medium Theory
5. Results and Discussion
5.1. MG Approximation of GNP-Based Composites Permittivity
5.2. Imaginary Permittivity Peak in Percolated Mixed-Filler Composites
6. Conclusions
Author Contributions
Funding
Acknowledgments
Conflicts of Interest
Abbreviations
MWCNT | Multi-walled carbon nanotube |
GNP | Graphene nanoplatelets |
PLA | Polylactic acid |
TEM | Transmission electronic microscopy |
AR | Aspect ratio |
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Parameter | Value |
---|---|
Glass transition temperature , °C | 65 |
Cold crystallization temperature Tcc, °C | 87–92 |
Melting temperature Tm , °C | 175 |
Melt crystallization temperature Tg, °C | 105 |
Crystallinity, % | 30 |
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Gorokhov, G.; Bychanok, D.; Gayduchenko, I.; Rogov, Y.; Zhukova, E.; Zhukov, S.; Kadyrov, L.; Fedorov, G.; Ivanov, E.; Kotsilkova, R.; et al. THz Spectroscopy as a Versatile Tool for Filler Distribution Diagnostics in Polymer Nanocomposites. Polymers 2020, 12, 3037. https://doi.org/10.3390/polym12123037
Gorokhov G, Bychanok D, Gayduchenko I, Rogov Y, Zhukova E, Zhukov S, Kadyrov L, Fedorov G, Ivanov E, Kotsilkova R, et al. THz Spectroscopy as a Versatile Tool for Filler Distribution Diagnostics in Polymer Nanocomposites. Polymers. 2020; 12(12):3037. https://doi.org/10.3390/polym12123037
Chicago/Turabian StyleGorokhov, Gleb, Dzmitry Bychanok, Igor Gayduchenko, Yuriy Rogov, Elena Zhukova, Sergei Zhukov, Lenar Kadyrov, Georgy Fedorov, Evgeni Ivanov, Rumiana Kotsilkova, and et al. 2020. "THz Spectroscopy as a Versatile Tool for Filler Distribution Diagnostics in Polymer Nanocomposites" Polymers 12, no. 12: 3037. https://doi.org/10.3390/polym12123037